Журнал Российского общества по неразрушающему контролю и технической диагностике
The journal of the Russian society for non-destructive testing and technical diagnostic
 
| Русский Русский | English English |
 
Главная
23 | 11 | 2024
2019, 04 April

DOI: 10.14489/td.2019.04.pp.058-062

 

Zaitsev A. V., Kaminsky O. I., Makarevich K. S., Kirichenko E. A., Pyachin S. A., Mokritskii B. Yа.
INSTALLATION FOR CATALYTIC ACTIVITY RESEARCH OF POWDER PHOTOCATALYSTS
(pp. 58-62)

Abstract. To study the activity of powder catalysts in the photo-decomposition reactions of organic pollutants in aqueous solutions, an automated installation has been developed, which combines photo-reaction and measurement cells. The installation provides the ability to irradiate the test solution simultaneously with the visible-ultraviolet light of the optical spectrum or the light of one of these ranges. Methylene blue dye was used as a model pollutant. The dye decomposition rate was determined by measurement of the optical density of the aqueous solution and the calibration concentration dependence. The measuring unit consists of a semiconductor laser with  = 650 nm, a photoresistor and a signal processing system. To maintain fine powders in the upper irradiated layer, a magnetic stirrer is used, and to maintain coarse particles, a piston – oscillating mechanism is used. The results at the application of the developed installation to study the properties of strontium bismuth as promising photocatalyst, the absorption region of which lies in the visible part of the spectrum, are presented.

Keywords: measuring installation, photocatalysis, photocatalysts, photometry, kinetics, conversion degree.

 

A. V. Zaitsev, O. I. Kaminsky, K. S. Makarevich, E. A. Kirichenko, S. A. Pyachin (Institute of Materials Science, Khabarovsk Scientific centre, Far Eastern Branch, the Russian Academy of Science, Khabarovsk, Russia) E-mail: Данный адрес e-mail защищен от спам-ботов, Вам необходимо включить Javascript для его просмотра. , Данный адрес e-mail защищен от спам-ботов, Вам необходимо включить Javascript для его просмотра. , Данный адрес e-mail защищен от спам-ботов, Вам необходимо включить Javascript для его просмотра. , Данный адрес e-mail защищен от спам-ботов, Вам необходимо включить Javascript для его просмотра. , Данный адрес e-mail защищен от спам-ботов, Вам необходимо включить Javascript для его просмотра.
B. Yа. Mokritskii (Komsomolsk-na-Amure State University, Komsomolsk-na-Amure, Russia) E-mail: Данный адрес e-mail защищен от спам-ботов, Вам необходимо включить Javascript для его просмотра.

 

 

1. Artem'ev Yu. M., Ryabchuk V. K. (1999.) Introduction to heterogeneous photocatalysis. Saint Petersburg: Izdatel'stvo Sankt-Peterburzhskogo universiteta. [in Russian language]
2. Kryukov A. I., Stroyuk A. L., Kuchmiy S. Ya., Pohodenko V. D. (2013). Nanophotocatalysis. Kiev: Akademperiodika. [in Russian language]
3. Gao X., Wang Z., Zhai X. et al. (2015). The synthesize of lanthanide doped BiVO4 and its enhanced photo-catalytic activity. Journal of Molecular Liquids, Vol. 211, pp. 25-30.
4. Li X., Zheng R., Luo Q. et al. (2015). Cyclized polyacrynitrile modified Ag3PO4 photocatalysts with enhanced photocatalytic activity under visible-light irradiation. Applied Surface Science, Vol. 356, pp. 941-950.
5. Li R., Gao X., Fan C. et al. (2015). Facile approach for the tunable fabrication of BiOBr photocatalystswith high activity and stability. Applied Surface Science, Vol. 355, pp. 1075-1082.
6. Alekseev I. S., Miklis N. I. (2013). Study of the properties of photocatalytic TiO2 nano-coatings for air purification from organic solvent vapors. Vestnik Vitebskogo gosudarstvennogo tekhnologicheskogo universiteta, 24, pp. 23-25. [in Russian language]
7. Liao X., Chen J., Wang M. et al. (2016). Enhanced photocatalytic and photoelectrochemical activities of SnO2/SiC nanowire heterostructure photocatalysts. Jour-nal of Alloys and Compounds, Vol. 658, pp. 642-648.
8. He Y. M., Wu Y., Sheng T. L., Wu X. T. (2010). Photodegradation of acetone over V–Сd–O composite catalysts under visible-light. Journal of Hazardous Materials, 180, pp. 675-682.
9. Makarevich K. S., Zaitsev A. V., Kaminsky O. I. et al. (2018). Catalytic Activity of a Composition Based on Strontium Bismuthate and Bismuth Carbonate at the Exposure to the Light of the Visible Range. International Journal of Chemical Engineering, Vol. 2018, ID 4715629.
10. Shtarev D. S., Shtareva A. V., Zaytsev A. V. (2014). Wastewater treatment of enterprises from petroleum products: experience of using photocatalysts of visible light based on bismuthates of alkaline-earth metals. Ekolo-gicheskiy vestnik nauchnyh tsentrov Chernomorskogo ekonomicheskogo sotrudnichestva, (4), pp. 88-92. [in Russian language]
11. Makarevich K. S., Zaytsev A. V., Kaminskiy O. I. et al. (2017). Formation and study of the composition of SrBi4-уO7-z / ½ (BiO) 2CO3 in the process of photocatalytic degradation of methylene blue. Physics: fundamental and applied research, education, materials of the XV regional scientific conference: collection of articles, pp. 107-110. Blagoveshchensk. [in Russian language]
12. Lamba R., Umar A., Mehta S. K., Kumar Kansal S. (2015). ZnO doped SnO2 nanoparticles heterojunction photocatalyst forenvironmental remediation. Journal of Alloys and Compounds, Vol. 653, pp. 327-333.
13. Zheng J.-Q., Zhu Y.-J., Xu J.-S. et al. (2013). Microwave-assisted rapid synthesis and photocatalytic activity of mesoporous Nd-doped SrTiO3 nanospheres and nano-plates. Materials Letters, Vol. 100, pp. 62-65.
14. Thomas J., Radhika S., Yoon M. (2016). Nd3+-doped TiO2 nanoparticles incorporated with heteropoly phosphotungstic acid: A novel solar photocatalyst for degradation of 4-chlorophenol in water. Journal of Molecular Catalysis A: Chemical, Vol. 411, pp. 146-156.

 

 

This article  is available in electronic format (PDF).

The cost of a single article is 350 rubles. (including VAT 18%). After you place an order within a few days, you will receive following documents to your specified e-mail: account on payment and receipt to pay in the bank.

After depositing your payment on our bank account we send you file of the article by e-mail.

To order articles please copy the article doi:

10.14489/td.2019.04.pp.058-062

and fill out the  form  

 

 

 
Rambler's Top100 Яндекс цитирования